在冶金工業(yè)的精密化學(xué)體系中，精萘作為一種關(guān)鍵有機(jī)原料，正悄然推動(dòng)著金屬提純、性能優(yōu)化與工藝革新。其獨(dú)特的分子結(jié)構(gòu)與化學(xué)特性，使精萘在鋼鐵冶煉、有色金屬加工及特種合金制備等領(lǐng)域，展現(xiàn)出不可替代的應(yīng)用價(jià)值。

　　In the precision chemical system of the metallurgical industry, refined naphthalene, as a key organic raw material, is quietly promoting metal purification, performance optimization, and process innovation. Its unique molecular structure and chemical properties make refined naphthalene irreplaceable in fields such as steel smelting, non-ferrous metal processing, and special alloy preparation.

　　一、精萘的化學(xué)特性與冶金應(yīng)用基礎(chǔ)

　　1、 Chemical properties and metallurgical application basis of refined naphthalene

　　精萘是由兩個(gè)苯環(huán)稠合而成的多環(huán)芳烴，其分子平面結(jié)構(gòu)賦予它獨(dú)特的物理化學(xué)性質(zhì)：

　　Naphthalene  is a polycyclic aromatic hydrocarbon formed by the condensation of two benzene rings, and its molecular planar structure endows it with unique physical and chemical properties

　　高碳?xì)浔扰c熱穩(wěn)定性

　　High carbon to hydrogen ratio and thermal stability

　　精萘碳含量高達(dá)93.7%，在高溫環(huán)境下（>80℃）開始升華，這一特性使其成為冶金反應(yīng)中的優(yōu)質(zhì)碳源。在電弧爐煉鋼中，精萘作為增碳劑，可精確調(diào)控鋼液碳含量，誤差范圍控制在±0.01%以內(nèi)。

　　The carbon content of refined naphthalene is as high as 93.7%, and it begins to sublime at high temperatures (>80 ℃), making it a high-quality carbon source in metallurgical reactions. In electric arc furnace steelmaking, refined naphthalene serves as a carbon additive, which can accurately regulate the carbon content of the steel liquid, with an error range controlled within ± 0.01%.

　　還原性與選擇性

　　Reductability and selectivity

　　在缺氧條件下，精萘可脫氫生成自由基，作為溫和還原劑參與金屬氧化物還原。在銅火法精煉中，精萘能選擇性還原Cu?O而不影響其他雜質(zhì)相，使除氧效率提升25%。

　　Under hypoxic conditions, naphthalene can be dehydrogenated to generate free radicals, which act as mild reducing agents to participate in the reduction of metal oxides. In copper pyrometallurgical refining, refined naphthalene can selectively reduce Cu ? O without affecting other impurity phases, resulting in a 25% increase in deoxygenation efficiency.

　　表面活性與滲透性

　　Surface activity and permeability

　　精萘分子可通過π-π堆積吸附于金屬表面，降低界面張力。在鋁合金熔煉中，添加0.05%精萘可使氫氣排出效率提升40%，顯著減少針孔缺陷。

　　Naphthalene molecules can adsorb onto metal surfaces through π - π stacking, reducing interfacial tension. In aluminum alloy melting, adding 0.05% refined naphthalene can increase the hydrogen emission efficiency by 40% and significantly reduce pinhole defects.

　　二、精萘在冶金工藝中的核心作用

　　2、 The core role of refined naphthalene in metallurgical processes

　　精萘通過三種作用機(jī)制深度參與冶金過程：

　　Naphthalene is deeply involved in metallurgical processes through three mechanisms of action:

　　碳質(zhì)調(diào)整劑

　　Carbonaceous adjuster

　　在電爐煉鋼中，精萘作為增碳劑，通過噴吹系統(tǒng)直接注入鋼液。其高反應(yīng)活性使碳吸收率達(dá)95%以上，遠(yuǎn)超石墨電極的85%吸收率，特別適用于低碳鋼（C<0.25%）的成分精準(zhǔn)控制。

　　In electric furnace steelmaking, refined naphthalene is used as a carburizer and directly injected into the molten steel through a blowing system. Its high reactivity results in a carbon absorption rate of over 95%, far exceeding the 85% absorption rate of graphite electrodes, making it particularly suitable for precise control of the composition of low carbon steel (C<0.25%).

　　還原介質(zhì)載體

　　Reduction medium carrier

　　在鎳鐵合金生產(chǎn)中，精萘與氧化鎳混合制成球團(tuán)，在回轉(zhuǎn)窯內(nèi)進(jìn)行選擇性還原。精萘揮發(fā)產(chǎn)生的還原性氣氛，使鎳氧化物的還原溫度降低100-150℃，能耗下降20%。

　　In the production of nickel iron alloy, refined naphthalene is mixed with nickel oxide to form pellets, which are selectively reduced in a rotary kiln. The reducing atmosphere generated by the volatilization of refined naphthalene lowers the reduction temperature of nickel oxide by 100-150 ℃ and reduces energy consumption by 20%.

　　熔劑改性劑

　　Flux modifier

　　在連鑄保護(hù)渣中添加0.5-1.0%精萘，可調(diào)控渣系黏度與結(jié)晶溫度。通過DSC差熱分析顯示，精萘使保護(hù)渣的結(jié)晶溫度窗口拓寬15℃，有效防止鑄坯表面裂紋。

　　Adding 0.5-1.0% refined naphthalene to continuous casting slag can regulate the viscosity and crystallization temperature of the slag system. According to DSC differential thermal analysis, refined naphthalene widens the crystallization temperature window of the slag by 15 ℃, effectively preventing surface cracks on the casting billet.

　　三、精萘應(yīng)用的創(chuàng)新方向

　　3、 Innovative directions for the application of refined naphthalene

　　隨著冶金工藝的精細(xì)化發(fā)展，精萘的應(yīng)用場景持續(xù)拓展：

　　With the refinement of metallurgical processes, the application scenarios of refined naphthalene continue to expand

　　特種鋼冶煉

　　Special steel smelting

　　開發(fā)精萘基復(fù)合合金化劑，通過化學(xué)氣相沉積在鋼表面形成碳化物層。在軸承鋼（GCr15）處理中，可使碳化物均勻度等級提升2級，接觸疲勞壽命延長30%。

　　Develop a refined naphthalene based composite alloying agent to form a carbide layer on the surface of steel through chemical vapor deposition. In the treatment of bearing steel (GCr15), the uniformity level of carbides can be improved by 2 levels, and the contact fatigue life can be extended by 30%.

　　有色金屬提純

　　Purification of non-ferrous metals

　　在電子級銅箔生產(chǎn)中，采用精萘作為有機(jī)添加劑，通過電化學(xué)共沉積技術(shù)，使銅箔晶粒尺寸細(xì)化至0.5μm以下，達(dá)到A級銅箔標(biāo)準(zhǔn)（ISO 11950）。

　　In the production of electronic grade copper foil, refined naphthalene is used as an organic additive, and the grain size of the copper foil is refined to below 0.5 μ m through electrochemical co deposition technology, meeting the A-level copper foil standard (ISO 11950).

　　3D打印金屬粉體制備

　　Preparation of 3D printed metal powder system

　　在氣霧化制粉過程中，精萘作為表面活性劑，可降低熔融金屬表面張力20%。制得的鈦合金粉末流動(dòng)性指數(shù)（Hall流速）提升至35s/50g，滿足航空航天級增材制造要求。

　　In the process of aerosol powder production, refined naphthalene as a surfactant can reduce the surface tension of molten metal by 20%. The flowability index (Hall flow rate) of the produced titanium alloy powder has been increased to 35s/50g, meeting the requirements of aerospace grade additive manufacturing.

　　四、應(yīng)用安全與環(huán)?？刂?/p>

　　4、 Application Security and Environmental Control

　　精萘的揮發(fā)性與致癌性潛在風(fēng)險(xiǎn)，需通過工程控制實(shí)現(xiàn)安全應(yīng)用：

　　The volatility and potential carcinogenicity risks of refined naphthalene require engineering control to achieve safe application:

　　密閉輸送系統(tǒng)

　　Closed conveying system

　　采用氮?dú)獗Ｗo(hù)螺旋輸送機(jī)，使精萘在惰性氣氛下轉(zhuǎn)移，操作區(qū)域苯并[a]芘濃度控制在0.1μg/m?以下，遠(yuǎn)低于GBZ 2.1職業(yè)接觸限值。

　　Using nitrogen to protect the screw conveyor, the refined naphthalene is transferred in an inert atmosphere, and the concentration of benzo [a] pyrene in the operating area is controlled below 0.1 μ g/m?, far below the occupational exposure limit of GBZ 2.1.

　　廢氣處理裝置

　　Exhaust gas treatment device

　　配置蓄熱式熱氧化爐（RTO），對精萘熱解廢氣進(jìn)行高溫焚燒。實(shí)測顯示，VOCs去除效率達(dá)99.5%，二噁英排放濃度<0.05ng-TEQ/m?。

　　Configure a regenerative thermal oxidation furnace (RTO) to incinerate the waste gas from the pyrolysis of refined naphthalene at high temperatures. Actual testing shows that the removal efficiency of VOCs reaches 99.5%, and the concentration of dioxin emissions is less than 0.05ng-TEQ/m?.

　　應(yīng)急處置方案

　　Emergency response plan

　　建立精萘泄漏快速響應(yīng)機(jī)制，配備活性炭吸附毯與化學(xué)中和劑。模擬演練表明，從泄漏檢測到污染控制可在15分鐘內(nèi)完成，環(huán)境影響范圍控制在5米半徑內(nèi)。

　　Establish a rapid response mechanism for naphthalene leakage, equipped with activated carbon adsorption blanket and chemical neutralizer. Simulation exercises show that the process from leak detection to pollution control can be completed within 15 minutes, and the environmental impact range is controlled within a 5-meter radius.

　　精萘在冶金行業(yè)的應(yīng)用，是化學(xué)科學(xué)與材料工程的交叉創(chuàng)新。通過精準(zhǔn)調(diào)控其反應(yīng)特性，精萘已成為金屬提純、組織控制、性能優(yōu)化的關(guān)鍵變量。隨著綠色冶金與智能制造的推進(jìn)，精萘的應(yīng)用將向功能化、精細(xì)化方向發(fā)展，持續(xù)賦能冶金工業(yè)的高質(zhì)量轉(zhuǎn)型。這種化學(xué)物質(zhì)的深度應(yīng)用，不僅展現(xiàn)了材料科學(xué)的魅力，更推動(dòng)了現(xiàn)代冶金工藝向更高效、更環(huán)保的方向邁進(jìn)。

　　The application of refined naphthalene in the metallurgical industry is a cross innovation between chemical science and materials engineering. By precisely regulating its reaction characteristics, refined naphthalene has become a key variable for metal purification, tissue control, and performance optimization. With the advancement of green metallurgy and intelligent manufacturing, the application of refined naphthalene will develop towards functionalization and refinement, continuously empowering the high-quality transformation of the metallurgical industry. The deep application of this chemical substance not only showcases the charm of materials science, but also promotes modern metallurgical processes towards greater efficiency and environmental friendliness.

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